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DISCOVERY OF VULCANIZATION (1840s) TO
ABOUT 1905
(BRAZILIAN RUBBER BOOM)
Vulcanization
Unvulcanized rubber suffers from softening at high ambient
temperatures and hardening at low temperatures: anyone who
has owned crepe-soled footwear will be aware of this. Ways
were sought to overcome this by treating the rubber with
all sorts of chemicals, eventually (in 1839) Charles Goodyear
found vulcanization by accidentally heating sulphur-coated
rubber which he observed became firm and was stable under
heating and cooling. The reader may wish to digress to learn
more about the importance of Goodyear.
Accelerators of vulcanization
Goodyear found that metallic oxides and carbonates speeded
vulcanization, but lead accelerators discoloured vulcanizates.
Rowley patented use of ammonia in vulcanization, but it
is doubtful if significance was noted. Gummiwerke Wundt
using red oil (crude aniline) by 1902 and acting as an accelerator.
Much of this emprical work was highly hazardous and appears
to have consisted of taking the by-products from coal distillation
(for town gas), using them to soften the rubber and finding
that they accelerated vulcanization and led to longer product
life (and presumably lessened the life of the workforce).
Rubber processing industry
The twin developments of mastication by Hancock and vulcanization
by Goodyear enabled the birth of the modern rubber industry.
By the 1850s rubber was being used in used in springs for
railway rolling stock and the pneumatic tyre had been invented
by R.W. Thomson in 1845, but had failed to be exploited.
This had to await another Scot: Dunlop.

This Victorian locomotive could attain
speeds of 80 mile/hour and ran on rubber springs
Wild trees fail to meet demand for rubber
The demand for rubber was growing and supplies were dependent
upon the collection of rubber from wild trees (Hevea brasiliensis)
growing in the Amazon Basin and to a limited extent upon
Funtumia elastica growing in the Congo region. There was
no control of the raw material as it was collected and processed
under primitive conditions (many of the trees were damaged
and the labourers were abused). Furthermore, it was anticipated
that the supply would eventually fail to meet the growing
demand. There was pressure from the early industrialists,
including Thomas Hancock, to establish more reliable supplies,
as well as from the geographer Clements Markam.
Clements Markham
Because Sir Clements Markham was a Civil Servant, there
has been a tendancy to consider him his as little more than
a bureaucrat and to underplay his contribution to the rubber
story. The digression places Markam's full contribution
within its rightful context. It is Markham who arranged
the expeditions to the Amazon to collect seeds and seedlings
for transfer to South Asia (and eventually to South East
Asia). Wickham usually receives most of the credit, but
other were involved, notably Collins and Cross (who has
probably received too little attention).
Brazilian Seeds
Henry Wickham successfully gathered 70,000 seeds in the
Amazon region and shipped them back to Britain where they
were germinated at Kew where some 2700 germinated. Seedlings
were shipped to Ceylon (now Sri Lanka) and to Singapore
and so into the Malayan Peninsular. The movement of these
materials by steam boat and steam train was a magnificent
achievement. Some commentators imply that the seeds were
"stolen" (and the local guides in Manaus state
this), but it would appear that the seeds were removed in
an official way, but that the implications of this transfer
failed to be appreciated until estate production in South
East Asia actually began - a long time after the seeds were
gathered.

Henry Wickhem
Plantation industry
The plantation industry was slow to establish itself, although
Hevea had flowered in Kuala Kangsar (Malaysia) in 1880 and
a Ficus elasica plantation had been established in Indonesia
in 1861. Investment in plantations had to await the demand
created by pneumatic tyres and motoring. Henry Ridley, who
did much to refine tapping methology, attempted to encourage
the establishment of plantations. There are tales that Ridley
used to carry rubber seeds in his pockets for distribution
to potential planters in what was then Malaya. Small scale
plantings were made in several West African countries during
the 1890s.

Henry Ridley
Outlets for rubber
By the middle of the nineteenth century there were many,
and varied, outlets for natural rubber. These included seals
for sewers; conveyor and transmission belting; flooring;
many items associated with clothing; inflatable boats and,
perhaps most interesting of all, the use of natural rubber
as a spring material in railway and road vehicles. The illustrations
show some early examples. The ever-eager Hancock published
a book which lists many of the Victorian innovations, including
some of those made from ebonite (many of which to be exhibited
at the Great Exhibition in London in 1851).
Pneumatic tyres
The story of the Scottish vet (John Boyd Dunlop) who assisted
with his wee lad's tricycling by inventing the pneumatic
tyre in 1888 is well-known. It is less well-known that the
innovative activity took place in Belfast (it was the Irish
stone setts which hurt the boy), and not in Ayrshire (Dunlop
was born in the village of Dreghorn, between Kilmarnock
and Ardrossan). This created a new demand for rubber as
cycling became popular, but the real demand came from motoring
which developed during the 1890s and becoming fully viable
in the next period.
The Michelin brothers were the major entrepreneurs as they
encouraged the use of pneumatic tyres for early racing vehicles,
notably in the 1895 Paris to Bordeaux race. Progress in
Britain was inhibited by the need for a man with a red flag
to walk in front of road motor vehicles.
New industrialists
Seiberling founded Goodyear Tire & Rubber Co in Akron
in 1898 (the company is based on the name of the inventor,
and is not related to the inventor) and in 1899 Harvey Firestone
created the Firestone Tire & Rubber Co.: the latter
was eventually to be acquired by the Japanese Bridgestone
Corporation. The United States Rubber Co had been established
in 1892 (it is a now a part of Continental). Even earlier
(1872) B.F. Goodrich had been founded: it became a major
tyre company, but now concentrates upon the supply of synthetic
rubber and other chemicals.
Rapid growth in demand
The use of motor transport grew rapidly especially in the
USA. Early tyres had a very short life. Demand for rubber
grew and the price went sky high. This encouraged the rapid
growth of rubber plantations in Ceylon, Malaya, the Dutch
East Indies and French Indochina (Sri Lanka, Malaysia, Indonesia
and Vietnam and Cambodia). It should be remebered that early
motor vehicles (horseless carriages) were intended for a
rich elite and the costs involved were regarded as being
trivial.
Smallholders
Many of the indigenous inhabitants of these areas had been
farming for generations. These farmers were perfectly capable
of perceiving a good idea and rapidly took up rubber cultivation
on a smaller scale. Eventually, such activity was ruthlessly
discouraged by the estate companies (most of whom were based
in the great financial centres, such as London and Paris),
with the assistance of the colonial administrators once
prices fell during the subsequent Inter-War period (1920s
and 1930s).
Rubber War & Brazilian rubber boom
Serier recorded the "rubber war" between Bolivia
and Brazil. At the end of the nineteenth century the Acre
region of the upper Amazon was a part of Bolivia. The inhabitants
of the Acre region attempted to obtain independence and
this led to conflict between Brazil and Bolivia. The Treaty
of Petropolis ceded the Acre region to Brazil in return
for a payment and the construction of a railway into the
region. Before the plantation industry got under way there
was a rapid increase in demand which was partially met by
a ruthless exploitation of the wild Hevea stands in the
Amazon Basin. There was a ruthless exploitation of labour
and of the trees. The magnificent opera house in Manaus
is a relic of this period.
Guayule
In 1901 William Lawrence discovered how to extract from
guayule. This desert shrub grows in Northern Mexico and
the neighbouring regions of the USA. Until the full impact
of plantation rubber from Asia became evident in the market
place guayule was able to compete due to the high rubber
prices prevailing before then.
Summary (so far)
The above very brief history of the rubber industry up to early
twentieth century is intended to show that demand was a key factor
in the development of the industry.
>Part 3
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